Mascarpone is a lovely substance…a thick triple-cream cheese that tastes of sweet cream with a tangy finish. It is far too rich to eat more than a spoonful or two straight up, but it is indispensable as an ingredient. A few spoonfuls stirred into a soup, pasta or risotto will elevate it from good to sublime. It makes an amazingly creamy and rich ice cream, tames the sweetness of caramel, and stabilizes whipped cream.
Mascarpone can easily be made at home from heavy cream (pasteurized produces a better product than ultra pasteurized) and tartaric acid (the primary acid found in wine–can be purchased online or at a wine-making supply store). It takes less than 10 minutes to prepare, but it must thicken and drain for 12 hours before it can be used.
Here’s how:
Mascarpone
2 cups heavy cream
1/8 teaspoon tartaric acid
Heat cream in a heavy saucepan to 180 degrees F. over medium-high heat, being careful that it does not scorch. Remove from heat as soon as it comes up to temperature and stir in the tartaric acid. Continue stirring for 1-2 minutes. Transfer to a glass or plastic container and refrigerate for 2 hours. At this point, it should have thickened significantly. Set a sieve over a bowl and line it with a triple thickness of cheesecloth and pour in mascarpone. Let drain for an additional 10 hours in the refrigerator.
Yesterday, I found myself with a fresh supply of mascarpone and a question that I have been pondering: Could mascarpone be caramelized?
I knew that I could stir in some burnt sugar and cook it down a bit , but I didn’t want to swing it that far into the sweet zone. What I wanted was to maintain the balance of sweet and tart, but deepen the flavor; make it more complex. But if I didn’t add sugar…would it still caramelize? Some would argue that the absence of sugar would instead cause the milk solids to toast (as in browned butter), but heavy cream does contain some sugar (16 grams per cup), so I got busy…
I packed mascarpone into a half pint mason jar, leaving an inch of headroom at the top, then sealed it with a lid and band. I then placed it on a folded towel in a pressure cooker and poured in about 3" of water, sealed the cooker and and brought it up to pressure. Worried about the water level, I decided to check it after 30 minutes. (My paranoia about letting the water bath dry out stems from a dulche de leche incident a few years ago involving a can of sweetened, condensed milk in a saucepan and one distraction too many…I’m still cleaning that mess up.) The water level had gone down about an inch, which I replaced, and it was just starting to take on color. I placed it back in the cooker for another 30 minutes. The color had noticeably deepened and it appeared to have retained its creamy texture, so I decided to stop there. As soon as it had cooled, I popped the lid and there it was…the sweet, nutty, toasty aroma and flavor that I was looking for. I now had a product that was familiar in texture and mouth feel, yet more complex and nuanced in flavor to play with.
Heady with success, I wondered what else could Be caramelized. I put every dairy product that I had on hand into mason jars and processed them in the same way. Here’s the results:
hits deepened color, taste and aroma, unaltered texture
whole milk
processed for 90 minutes

heavy cream
processed for 90 minutes

canned evaporated milk
processed for 90 minutes
misses deepened color, taste and aroma, altered texture

lebne
processed for 60 minutes
(formed soft curds that could be whipped until creamy, but remained slightly grainy)

sour cream
processed for 60 minutes
(formed firm curds; texture could not be restored by whipping)
conclusions It appears that the cultured products curdled under the intense heat/prolonged cooking, while the uncultured ones achieved the desired effect. This is just a rudimentary observation…I wish that I knew more about the science at play here. Regardless, I am happy with the 4 new products that I have here. I am especially excited about the versatility of heavy cream and what it can produce: flans, custards, whipped cream and maybe even butter. Back to work play.
UPDATE: Chemistry professor and author Robert L. Wolke writes in his book What Einstein Told His Cook, "the word caramelization should be reserved for the browning of sugar- any kind of sugar- in the absence of protein. When sugars or starches occur together with proteins as they do in onions, breads, and meats, the browning is mostly due to the Maillard reaction, not caramelization."
So. I guess that I should refer to these products as Maillard milk.